Abstract
Liquid crystals possess a wide range of applications in modulating infrared (IR) light and have drawn great interest especially in near-infrared shielding and passive radiative cooling. Here, a composite structure containing polymer dispersed liquid crystals (PDLC) with antimony doped tin oxide and cesium tungsten oxide loaded bilayer nanofiber membranes with IR shielding properties is proposed. The composite film and the blank liquid crystal cell are irradiated simultaneously under IR light, and the temperature detector shows that the average temperature drop of the PDLC composite film in the scattered state and the fully transparent state over the blank sample are 6.8 °C and 4.1 °C, respectively. More importantly, the dynamic IR shielding properties of the composite films are demonstrated by patterning the nanofiber films. In addition, this organic/inorganic hybrid PDLC system not only modulates IR light, but also exhibits excellent electro-optical properties, aging resistance, flexural stability (1000 cycles), and tensile resistance. The composite film combines ease of preparation with compatibility for industrial-scale roll-to-roll or continuous manufacturing processes, highlighting the great potential of PDLC for applications in tunable optical heat transport materials.
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