Atmospheric Mercury Concentrations and Isotopic Compositions Impacted by Typical Anthropogenic Mercury Emissions Sources.

Abstract

Coal-fired power plants (CFPPs) and cement plants (CPs) are important anthropogenic mercury (Hg) emission sources. Mercury speciation profiles in flue gas are different among these sources, leading to significant variations in local atmospheric Hg deposition. To quantify the impacts of Hg emissions from CFPPs and CPs on local-scale atmospheric Hg deposition, this study determined concentrations and isotopes of ambient gaseous elemental mercury (GEM), particulate-bound mercury (PBM), and precipitation total Hg (THg) at multiple locations with different distances away from a CFPP and a CP. Higher concentrations of GEM and precipitation THg in the CFPP area in summer were caused by higher Hg emission from the CFPP, resulting from higher electricity demand. Higher concentrations of GEM, PBM, and precipitation THg in the CP area in winter compared to those in summer were related to the higher output of cement. Atmospheric Hg concentration peaked near the CFPP and CP and decreased with distance from the plants. Elevated GEM concentration in the CFPP area was due to flue gas Hg0 emissions, and high PBM and precipitation Hg concentrations in the CP area were attributed to divalent Hg emissions. It was estimated that Hg emissions from the CFPP contributed 58.3 ± 20.9 and 52.3 ± 25.9% to local GEM and PBM, respectively, and those from the CP contributed 47.0 ± 16.7 and 60.0 ± 25.9% to local GEM and PBM, respectively. This study demonstrates that speciated Hg from anthropogenic emissions posed distinct impacts on the local atmospheric Hg cycle, indicating that Hg speciation profiles from these sources should be considered for evaluating the effectiveness of emission reduction policies. This study also highlights the Hg isotope as a useful tool for monitoring environmental Hg emissions.