Abstract

A three-dimensional and isothermal anode relative humidity (ARH) model is presented and used to study the anode inlet humidity effects on the fastest power attenuation single cell in a vehicle fuel cell stack. The ARH model is based on the phenomenon that the anode is more sensitive than the cathode to water flooding. The pressure drop is considered in the ARH model, and saturation pressure is established by a pressure drop. Based on the pressure drop and relative humidity, simulations and tests are completed. First, the geometric model and computational grids are established, based on real structure of the proton exchange membrane fuel cell (PEMFC). Second, single cell distribution in the stack, test schematic and experimental conditions are demonstrated. Finally, polarization curves with 10 cells are displayed and discussed under these conditions that working temperature 70 °C, and diverse relative humidity (40%, 55%, 70%, 85%, and 100%). The test results of 34 cm2 fuel cell stack are compared against simulation results. The results show that C10 (the single cell with the farthest distance from the gas inlet) power attenuation is the fastest and that its performance is the poorest under the experimental conditions. The polarization curves predicted by the ARH model indicate fairly good coherence with the experimental results, compared against the Fluent original model. The ARH model calculation deviation is 28% less than the Fluent model at 360 mA·cm−2 for a relative humidity of 85%. The current density distribution is almost uniform, and membrane water content is negatively affected by high humidity.

Highlights

  • Hydrogen as a renewable clean energy is widely used in hydrogen internal combustion engines and proton exchange membrane fuel cell (PEMFC) vehicles, due to the excessive consumption of fossil fuels and the emissions of pollutants [1,2,3]

  • The pressure drop is considered in the calculation of relative humidity in the anode relative humidity (ARH) model, so that the relative humidity is obtained by inlet pressure and saturation pressure

  • Pressure drop is considered in the calculation of relative humidity in the ARH model, so

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Summary

Introduction

Hydrogen as a renewable clean energy is widely used in hydrogen internal combustion engines and proton exchange membrane fuel cell (PEMFC) vehicles, due to the excessive consumption of fossil fuels and the emissions of pollutants [1,2,3]. One commonly used method is liquid water humidification, which is simple and efficient; this method has serious flooding problems, which leads to the deterioration of PEMFC performance Another method is bubble humidification, the issue for which is controlling the temperature and humidity when the gas enters. R Eckl et al [24] revealed that gas humidification played a crucial role in the low power range for high operating temperatures They explained the physical and chemical mechanism applications by observing the experimental phenomenon of fuel cell in two kinds of extreme cases, dry and flooded. The relative humidity influence on PEMFC vehicle operation has caused Jeon et al [27] great interests They concluded that low humidity was beneficial in reducing costs and the overall weight of the humidifier in the external cell cathode, according to serious flooding phenomena. The counters of fuel cell species are displayed and analyzed

ARH Model Description
Simulation Schematic
Geometry and Mesh
Apparatus and Schematic
Polarization Curves with 10 Single Cells
Polarization
The Fastest Power Attenuation Single Cell
Contours of Fuel Cell Species Distribution
Conclusions
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