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https://doi.org/10.1021/ol900447n
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Cite Journal: Organic Letters |  Publication Date: Apr 8, 2009 |
 Citations: 13 |
Affiliation: Kyoto University
A chiral ligand- and lithium amide-assisted asymmetric conjugate addition of lithium enolate of propionate to cyclopentenecarboxylate gave the corresponding lithium enolate, whose allylation gave the key intermediate of the marine alkaloid halichlorine as a single diastereomer with moderate enantioselectivity.
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