Assessment of the NO2 Spatio-Temporal Variability over Thessaloniki, Greece, Using MAX-DOAS Measurements and Comparison with S5P/TROPOMI Observations

Abstract

In this article, we investigate the spatio-temporal variability of tropospheric NO2 Vertical Column Densities (VCDs) and surface concentrations that were retrieved using Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements over Thessaloniki, Greece, for the period June 2020 to November 2022. The MAX-DOAS system captures the NO2 seasonal variability very well, reporting low concentrations during summer and higher concentrations in the winter, as well as the diurnal cycle with higher NO2 amounts in the morning followed by a reduction towards noon. The “weekend effect” is evident, with approximately 30% lower NO2 concentrations on the weekends compared to the working days. An excellent agreement is found with in situ data from a nearby air quality monitoring station with Pearson’s correlation coefficients ranging between R = 0.90 and R = 0.99. The spatial variability is assessed by comparing the NO2 concentrations at four azimuth viewing directions of the MAX-DOAS system. Despite the large variability due to short- and long-term temporal variations, higher NO2 concentrations of up to 25% (statistically significant at the 95% confidence level) are reported for the azimuth that crosses the entire city center and an urban area compared to those pointing towards the sea. The MAX-DOAS tropospheric NO2 columns are then compared to those measured by the TROPOspheric Monitoring Instrument (TROPOMI) on board the Sentinel-5P satellite. Despite the generally good correlation (R = 0.72 and R = 0.89 for the daily and monthly data, respectively), a clear underestimation of TROPOMI is found (approximately 55% in winter, 21% in spring and 40% during autumn and summer), mainly due to the much larger satellite footprint that provides a smoother perception of the NO2 concentration, while the MAX-DOAS measurements are more affected by local emissions.