Abstract
After introductory considerations of the various uses of coordination complexes containing tervalent phosphorus ligands and a discussion of the metalphosphorus bond, the complex-forming behaviour of the derivatives of various structures in the reaction with metal salts is considered. As to be proved by spectroscopic and magnetic data, the transition metal complexes of various structures, which depend on the substituents at the phosphorus atoms, are obtainable. The reactions of the primary and the secondary phosphines and of phosphine with carbonyls result in a series of substituted products, the constitution of which resembles that of the tertiary or polytertiary phosphines respectively.
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