Abstract
The title compound, μ-aqua-1:2κ2O-pentaaqua-1κ2O,2κ3O-μ-3,6-bis(6-methyl-2-pyridyl)pyridazine-1κ2N1,N6:2κ2N2,N3-chloro-1κCl-dinickel(II) trichloride trihydrate, [Ni2Cl(C16H14N4)(H2O)6]Cl3·3H2O, consists of two NiII atoms, a 3,6-bis(6-methyl-2-pyridyl)pyridazine molecule, four Cl atoms and nine water molecules. The two Ni atoms are octahedrally coordinated by N and Cl atoms, and by water molecules, and the three six-membered rings, a pyridazine and two picolines, are planar to within 0.181 (3) A. The crystal structure is stabilized by an intra- and intermolecular hydrogen-bonding scheme involving water–water and water–chlorine interactions.
Published Version
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