Abstract
In the title compound, [Mn(NCS)2(C13H19N3O)(H2O)], the Schiff base acts as an N,N′,N"-tridentate ligand, forming two five-membered chelating rings with the MnII atom. The distorted octahedral geometry around the metal atom is completed by two cis-positioned N-bound thiocyanate ligands and one water molecule. In the crystal, adjacent molecules are linked through O—H⋯O, O—H⋯S and C—H⋯S hydrogen bonds into a three-dimensional supra-molecular structure. An intramolecular C—H⋯O hydrogen bond also occurs.
Highlights
In the title compound, [Mn(NCS)2(C13H19N3O)(H2O)], the Schiff base acts as an N,N0,N"-tridentate ligand, forming two five-membered chelating rings with the MnII atom
Adjacent molecules are linked through O—HÁ Á ÁO, O—HÁ Á ÁS and C—HÁ Á ÁS hydrogen bonds into a three-dimensional supra-molecular structure
Symmetry codes: (i) x+1, y, z; (ii) x, −y+1/2, z−1/2; (iii) −x, −y+1, −z+2
Summary
Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.003 A; R factor = 0.037; wR factor = 0.082; data-to-parameter ratio = 18.2. In the title compound, [Mn(NCS)2(C13H19N3O)(H2O)], the Schiff base acts as an N,N0,N"-tridentate ligand, forming two five-membered chelating rings with the MnII atom. The distorted octahedral geometry around the metal atom is completed by two cis-positioned N-bound thiocyanate ligands and one water molecule. Adjacent molecules are linked through O—HÁ Á ÁO, O—HÁ Á ÁS and C—HÁ Á ÁS hydrogen bonds into a three-dimensional supra-molecular structure. An intramolecular C—HÁ Á ÁO hydrogen bond occurs. Related literature For the isostructural Co(II) complex, see: Suleiman Gwaram et al (2011)
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