Abstract
In the oxido-centered title compound, [Fe2Mn(C2HCl2O2)6O(C4H8O)(H2O)2], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloroacetate anions, and is in a triangular configuration. Two of the metal atoms are each coordinated by a water molecule, whereas the third is coordinated by a tetrahydrofuran molecule. In the crystal, adjacent molecules are linked by O—H⋯O and O—H⋯Cl hydrogen bonds across centers of inversion, generating a hydrogen-bonded chain along the c axis. The MnII atoms are disordered with respect to the FeIII atoms, and the same metal site is occupied by 1/3Mn + 2/3Fe.
Highlights
Structure Reports OnlineKey indicators: single-crystal X-ray study; T = 295 K; mean (C–C) = 0.012 A; disorder in main residue; R factor = 0.063; wR factor = 0.207; data-to-parameter ratio = 19.4. Mr = 1058.34 Triclinic, P1 a = 9.380 (1) Ab = 13.316 (1) Ac = 15.432 (1) A = 90.131 (1)
In the oxido-centered title compound, [Fe2Mn(C2HCl2O2)6O(C4H8O)(H2O)2], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloroacetate anions, and is in a triangular configuration
Two of the metal atoms are each coordinated by a water molecule, whereas the third is coordinated by a tetrahydrofuran molecule
Summary
Key indicators: single-crystal X-ray study; T = 295 K; mean (C–C) = 0.012 A; disorder in main residue; R factor = 0.063; wR factor = 0.207; data-to-parameter ratio = 19.4. Mr = 1058.34 Triclinic, P1 a = 9.380 (1) Ab = 13.316 (1) Ac = 15.432 (1) A = 90.131 (1)
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