Abstract
It is shown in the approximation of additivity of the molecule interaction potential in a fluid that the relationship uv ≈ const is satisfied approximately on the saturation line. The deviation from experiment is 10–30% for the majority of fluids, and 5% for crystalline argon. The mentioned deviation of uv from experiment is explained by multiparticle molecule interaction not being taken into account in fluids, consequently, the role of the multiparticle interaction in condensed media can be assessed according to the magnitude of the deviation from experiment.
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