Abstract
Abstract Folded chains of syndiotactic polystyrene located on the surface of its solution-grown crystals (SGCs) have been observed on nano scale by use of atomic force microscopy (AFM). Transmission electron micrographs of the SGCs on the mesoscopic scale exhibited truncated-lozenge platelets accompanied by a sharp electron diffraction pattern of the β”-form. AFM images of selected areas on the SGC surface indicated folded chains existing periodically on the surface with c. 1.3 to 1.4 nm spacing, suggesting that the polymer chains are aligned in parallel with the {230} growth faces of SGC.
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