Apportioning sources of natural and anthropogenic organic matter in sediment from Lake Shihwa: An integrated approach using molecular ratios and compound-specific stable-isotope analysis

Abstract

We tested an integrated multi-isotopic analysis framework to quantitatively estimate anthropogenic organic matter (OM) loads in different land-use types of a watershed (Lake Shihwa, South Korea). The isotopic signatures of increased bulk-element abundances in urban areas and industrial complexes may reflect the mixed contributions of natural and anthropogenic sources. Together with the predominant abundance of n-alkanes and polycyclic aromatic hydrocarbons at both boundaries, specific indices derived from their abundance may be indicative of mixed contributions from terrestrial plants, petroleum, and combustion deposited through various pathways (e.g., atmospheric deposition, outfall pipes, and surface runoff). Based on these properties, compound isotopic signatures (δ13CC27+C29+C31, δ13CFl, δ13CPyr, δ13CBaA+Chry, δ13CIcdP, δ13CBghiP,) for both land-use types may provide significant evidence of an increase in anthropogenic derived-OM loads (> 90 %) in Lake Shihwa. This approach suggests that total organic carbon–weighted source apportionments can provide useful quantitative estimates of OM loads within complex river systems.