Application of SnO2/Alumina Nanocatalyst in Removal of Naphthenic Acids from Crude Oil

Abstract

The separation of naphthenic acids from crude oil is difficult, and the presence of such materials in crude oil reduces its value. In this work, using catalytic esterification with methanol, naphthenic acids of crude oil were removed to reduce their harmful effects. SnO2/γ-Al2O3 nanocatalyst was synthesized and used to convert naphthenic acids of crude oil in a fixed bed catalytic reactor. The nanocatalyst was characterized by the X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and Brunauer–Emmett–Teller (BET) surface area techniques. The XRD revealed the formation of rutile SnO2 on alumina, and the FESEM approved that the catalyst is comprised of nanoparticles with a diameter in the range of 50 to 90 nm. The BET indicated that the catalyst has a mesopore structure with a surface area of 213.4 m2·g–1. The optimal conditions for the catalytic esterification process of naphthenic oil were determined. The temperature of the reduction of the total acid number (TAN) of crude oil ranged from 250 to 360 °C, and the TAN was reduced to less than 0.5 mg KOH/g in this temperature range. A methanol-to-oil ratio (M/O) of 2 wt %, a velocity space of 2.5 h–1, a reaction temperature of 300 °C, and atmospheric pressure were selected as the optimal conditions for the removal of naphthenic acids. Under these conditions, 83% of naphthenic acids was removed. The study indicated that SnO2/γ-Al2O3 could be a promising nanocatalyst for the reduction of total acid of crude oil under mild conditions.