Application of polyamide thin-film composite layered on polysulfone-GO/TiO2 mixed matrix membranes for removal of nitrotoluene derivatives from petrochemical wastewaters.

Abstract

Release of harmful organic intermediates or byproducts during the manufacture of petrochemical compounds is a serious problem in petrochemical plants. In this work, polysulfone membranes blended with GO/TiO2 nanocomposite were synthesized by phase inversion method and coated with a polyamide layer formed by interfacial polymerization to prepare a thin-film composite (TFC) sample. Analysis and characterization of the sample were carried out by XRD, FE-SEM, BET, FTIR/ATR, AFM, TGA, and zeta potential. Results indicated that incorporation of GO/TiO2 into the membrane structure enhanced porosity, surface roughness, and macrovoid formation along the cross-section of the sublayer and permeability of the membrane. The TFC membranes were applied to remove mononitrotoluene (MNT) and dinitrotoluene (DNT) as the basic intermediates of toluene diisocyanate (TDI). The membranes demonstrated high efficiency (> 90%) for the removal of MNT and DNT according to the charge exclusion mechanism and Donnan effect. Application of the TFC membrane for treatment of wastewater in the TDI plant showed that the removal of pollutants is variable in the range of 45-65% and 53-69% for the membrane with the highest flux and highest rejection in different transmembrane pressure, respectively.