Abstract
The kinetics of NO–CO reaction over Pt/Al 2O 3 catalyst was investigated at 150 °C at steady-state and under periodic condition. The steady-state experiments showed that the reaction order was 0.9 with respect to NO concentration and −0.7 with respect to CO concentration. A mechanism which satisfied the results was proposed. A bang–bang operation was conducted for periodic condition, where a square wave of NO concentration and CO concentration was applied. A deformation of NO concentration cycling pattern was observed at the outlet of a flow reactor under the periodic operation. The deformed pattern was reasonably well simulated by calculation. Kinetic parameters in the proposed mechanism were estimated by fitting the calculated pattern to the experimental one. The estimated parameters could reproduce the steady-state performance, as well as the periodic operation performance.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
