Application of hydrophilic ionic liquid treatment to the morphological observations of hydrated porous ceramic green bodies

Abstract

In this study, a simple and convenient method for observing the surface morphology of hydrated porous ceramic green bodies is proposed. The porous hyrdoxyapatite (HAp) green body was prepared by a gelcasting process and was dried in a humid chamber from 90 to 50% relative humidity at 25°C before subsequent treatment with a hydrophilic ionic liquid (IL). The surface morphology of the IL-treated porous HAp green body was observed using FE-SEM. The results showed that the pore morphology and microstructure of the HAp green body was readily observable without evidence of charging. The as-prepared sample showed pores approximately 300–600μm in diameter, which gradually contracted to approximately 200–400μm upon drying in the humid chamber. Following sintering at 1000°C, the pores had further contracted to approximately 100–300μm. The IL binds with the surrounding water to prevent the sample from drying in vacuum and acts as a conductive media, allowing the HAp ceramics to be observed in the electron microscope. In comparison to the micro-focused X-ray CT analysis, the fine pore structure (less than 100μm) could only be observed using FE-SEM when the porous body had also been subjected to the IL treatment.