Abstract
The possibility is considered of using headspace analysis in studies of chemical equilibria in solutions of volatile organic compounds. The main theoretical relationships for the determination of the constants of X + Y ⇄ XY type equilibria by the gas chromatographic analysis of equilibrated vapour above a solution are derived. New methods are proposed and have been checked experimentally for the measurement of the ionization constants of volatile organic compounds, and of the stability constants of metal complexes with unsaturated and aromatic hydrocarbons.
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