Applicability of monitoring data of Hg soil-atmosphere transport in an old mining area for exposure risk assessment

Abstract

Mercury (Hg) is a widespread pollutant that poses significant risks to both ecosystems and human health. While previous studies have evaluated Hg concentrations in soils, few have measured Hg emissions in areas with high Hg concentrations or related these measurements to estimates of exposure via air inhalation based on Hg flux values. This study addresses this gap by proposing the use of gaseous elemental Hg (GEM) flux measurements for exposure risk assessments, with a particular focus on the importance of inhalation exposure, which has implications for future risk management strategies. Sensitivity analysis of the site-specific exposure and risk estimation model revealed that the fraction of land area in surface water significantly impacted the estimated exposure through air inhalation. Additionally, the analysis showed that the GEM flux measured in situ in a high-Hg concentration area of Itomuka was not directly proportional to the Hg concentration, although the risk estimation model treated it as a function of concentration. Furthermore, we found that the flux values are influenced by both the fraction of land area in surface water and Hg concentration, indicating that this new flux-based indicator should be integrated into exposure risk assessments.