Abstract

In this study, a uniform and less defective ceramic coating was prepared on high Si content aluminium alloys by a sectionalized plasma electrolytic oxidation (PEO) mode. The PEO process of Al-9 wt. % Si binary alloy was performed under constant current mode followed by constant voltage mode. The surface micrographs and chemical compositions of different samples were analysed by scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. Micro-hardness and reciprocal-sliding testers were used to measure the coatings hardness and tribological performance. It was found that the sectionalized PEO mode could produce hard and anti-friction passive oxide layers with smaller holes and fewer cracks on the Al-Si alloy, comparing with the single constant current mode. In addition, the results of polarization curves and electrochemical impedance spectroscopy (EIS) tests conducted in 3.5 wt. % NaCl solution revealed that the coatings obtained by sectionalized PEO mode had a higher corrosion resistance and provided better corrosion protection for Al-Si alloy.

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