Abstract

Two series of metastable, cubic face-centered non-stoichiometric anti-glass tellurates of Y, La, and lanthanides have been found: Te-richer phases, containing tetravalent Te only, with compositions between Ln 2Te 6O 15 and Ln 4Te 7O 20 and lattice constants of 570−549 pm, and Ln-richer phases containing minor amounts of hexavalent Te, with Ln:Te ratios between 3:2 and 11:10, and lattice constants between 574 and 539 pm.

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