Anthropogenic Gadolinium Anomalies in an Alluvial Plain with On-site Wastewater Treatment Systems in Campinas, SP, Brazil

Abstract

Gadolinium anomalies have become a well-established marker for the pollution caused by wastewater, but there is not yet a standardized method to estimate the anomaly. Here, we compare four different published equations, distinct threshold values and reference normalizing values to estimate Gd anomalies by applying them to the results of a hydrochemical investigation in an alluvial aquifer with on-site sanitation systems. We measured traditional wastewater markers (such as electric conductivity, NO3_N, NH4–N, Cl-) and REE in groundwater samples collected from hand-dug wells in two seasons. The ratios of Gd normalized measured concentrations to Gd normalized geogenic concentrations (GdSN/Gd*) estimated with the various methods ranged from 0.7 to 2.8. It turned out that the choice of the equation and the threshold value can affect the decisions about anthropogenic pollution’s occurrence (or not). The normalizing values did not play a significant role in the decision. Based on measurement uncertainties and on the interpretation of hydrogeological conditions in the study area, a threshold value of 1.3 for defining anthropogenic Gd anomalies was deemed adequate for the study area. The occurrence of Gd anomalies higher than 1.8 in two wells, one in each season, reinforces the hypothesis that the groundwater is contaminated by the on-site sanitation systems in the study area, as intermittent detection of anthropogenic Gd is a characteristic of this pollution source.