Anisotropic alumina ceramics with isotropic optical properties

Abstract

Excellent mechanical and isotropic optical properties are achieved simultaneously from fully dense polycrystalline advanced alumina ceramics with a hexagonal crystal structure, which are optically anisotropic. A small amount (240 ppm) of ZrO₂ additive is used to synthesize the transparent alumina ceramics with an average grain size of 0.7 µm, and locally detected optical distortion (birefringence) is extremely minimized, less than 20 nm/pass. Total transmittance (86%) of the alumina ceramics (thickness = 0.3 mm) in ultraviolet (UV) to infrared (IR) regions is similar to that of commercial <i>c</i>-axis sapphire single crystals produced by Czochralski (CZ) method, while the extinction ratio in the visible wavelength area is over 25 dB. Like glass and the <i>c</i>-axis sapphire single crystals, the alumina ceramics can clearly display texts and images on liquid crystal display (LCD) screens. A grain boundary phase of nano-sized Al₂O₃–ZrO₂ composition (amorphous) is formed at the grain boundary of the advanced alumina ceramics, which enhances four-point bending strength and fracture toughness (<i>K</i>_IC) simultaneously to 921 MPa and 6.8 MPa·m^0.5, respectively, and hence the mechanical properties are superior to those of the sapphire single crystals.