Abstract

Hierarchical TiO2 nanoleafed nanorod thin film was successfully synthesized on the fluorine doped tin oxide glass substrate. For this purpose, the nanorods were coated on the TiO2 seeded substrate via the hydrothermal method. Then, nanoleafs were grown on the nanorods by aqueous chemistry. Field emission scanning electron microscopy, energy dispersive spectroscopy, and Raman spectroscopy were utilized for thin film characterization. The results clarified that anatase-phase nanoleafs were uniformly grown on the rutile-phase nanorods in the TiO2 coating. The photocatalytic performance of the thin film was determined by photodegradation of anionic and cationic organic pollutants, and the photocatalytic decomposition mechanisms of the dyes were discussed. The improved photocatalytic activity of TiO2 was ascribed to the photogenerated charges separation at the interface of rutile-nanorod/anatase-nanoleafs junctions and favorable light harvesting.

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