Abstract
In this study, we propose green/red bilayered freestanding phosphor film-capped white light-emitting diodes (W-LEDs) using InGaN blue LEDs and narrowband red and green phosphors to realize a wide color gamut in a liquid crystal display (LCD) backlight system. The narrowband K2SiF6:Mn4+ (KSF) red and SrGa2S4:Eu2+ (SGS) green phosphors are synthesized using a facile etching synthetic process and flux-aided solid state reaction under a H2S atmosphere, respectively, and the freestanding phosphor films are fabricated using a delamination method with water-soluble polymer, polystyrene sulfonic acid, PEDOT/PSS, and interlayered phosphor film. Various phosphor concentrations of green/red bilayered freestanding phosphor film-capped W-LEDs exhibit a correlated color temperature (CCT) and luminous efficacy range of 11,390 K ~6,540 K and 99 lm/W ~124 lm/W, respectively, with an applied current of 60 mA. The W-LED with green (12.5 wt%)/red (40 wt%) bilayered phosphor film, which exhibited luminous efficacy of 105 lm/W at the CCT of 8,330 K, is selected and the color gamut of the bare LED and phosphor RG and the filtered RGB triangle is calculated to be more than ~95% and ~86.4%, respectively, relative to the NTSC in the 1931 CIE color coordinates space.
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