Abstract
Rotational analyses have been performed on the emission spectra of the 0-0, 1-1, 2-2, and 3-3 bands of the β system ( c 1Φ - a 1Δ) of the TiO molecule, excited in a microwave discharge through a mixture of helium, oxygen and TiCl 4 vapor. Rotational constants were obtained for all the bands from which the following equilibrium constants were derived. Be ‘=0.52301±0.00008 cm −, αe ‘=0.00313±0.0006 cm −, re −=1.6391±0.0001 A Higher order constants, D v and H v , were calculated for the various vibrational levels.
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