Abstract
The TiO spectrum has been excited by a microwave discharge through a mixture of helium, oxygen, and TiCl4 vapor. A rotational analysis of a strong band at 5240.5 Å has shown that it is the 0,0 band of a transition from a new 1Δ state to the a1Δ state of the TiO molecule. The origin of the band is at ν0 = (19 068.95 ± 0.03) cm−1 and the rotational constants of the new 1Δ state are[Formula: see text]
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