Abstract
A multi-element soil geochemical survey was conducted over the conterminous United States from 2007–2010 in which 4,857 sites were sampled representing a density of 1 site per approximately 1,600 km2. Following adjustments for censoring and dropping highly censored elements, a total of 41 elements were retained. A logcentred transform was applied to the data followed by the application of a principal component analysis. Using the 10 most dominant principal components for each layer (surface soil, A-horizon, C-horizon) the application of random forest classification analysis reveals continental-scale spatial features that reflect bedrock source variability. Classification accuracies range from near zero to greater than 74% for 17 surface lithologies that have been mapped across the conterminous United States. The differences of classification accuracy between the Surface Layer, A- and C-Horizons do not vary significantly. This approach confirms that the soil geochemistry across the conterminous United States retains the characteristics of the underlying geology regardless of the position in the soil profile.
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