Abstract

Beyond the familiar resistance or impedance, immittance is a broad term for complex-valued quantities that define how current through a sample responds to voltage. Given the spectrum of immittance, one can construct an equivalent-circuit model that will reproduce it, but the model is not unique---and can even be misleading. The authors explain how to find the unique, physically meaningful equivalent circuit that allows direct extraction of physically relevant system parameters. Furthermore, the physics behind their method lays the foundation for exploiting the nonlinear response of systems in fields ranging from electrochemistry to biology to geology.

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