Abstract

A novel 3D coordination polymer [Cd2(cca)2(bib)3]⋅3H2O (1, H2cca=4-carboxycinnamic acid, bib=1,4-bis(imidazole)butane) has been synthesized. This compound exhibits an unusual two-fold interpenetrating polyrotaxane-like structure comprised of two interlocked sets of identical diamond nets.

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