An Unusual Cyanide Bridging Lanthanide-Transition Metal Complex that Contains the One-Dimensional Cationic Array {[(DMF)(16)Yb(6)(&mgr;(6)-O)(&mgr;(3)-OH)(8)(&mgr;-NC)Pd(&mgr;-CN)(CN)(2)](6+)}(infinity).

Abstract

A new type of lanthanide-Group(10) transition metal mixed ligand complex is produced in the redox reaction of YbCl2 with K2[Pd(CN)4]·H2O in DMF. This complex consists of a cationic, chainlike array...