Abstract
A new, simple one-pot synthesis of 1,1,4,4,4-pentafluorobut-1-ene CF3CH2CHCF2 (HFO-1345czf) (1) was developed. Reactivity of 1 was evaluated in copper(I)-catalyzed defluoroborylation with the following Suzuki-Miyaura cross-coupling of boryl(monofluoro)alkene and addition-elimination reactions with nucleophiles and electrophiles. Features of the chemical behavior of 1 are discussed.
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