An operation strategy for mitigating the degradation of solid oxide electrolysis cells for syngas production

Xiufu Sun,Yuliang Liu,Peter Vang Hendriksen,Ming Chen

doi:10.1016/j.jpowsour.2021.230136

Abstract

Three cells were tested under different conditions to mimic the situation with stacks arranged in gas flow series or parallel. The effects of reactant conversion ratio and inlet gas composition on the cell performance and durability were studied. The cells were operated under −1 A/cm2 at 800 °C for H2O + CO2 co-electrolysis. Flows were adjusted to realize the same overall production of syngas. Detailed electrochemical characterization was performed before, during and after the aging test and microstructural changes after aging were investigated. The results show that a gas-flow series arrangement is advantageous as it leads to reduced cell degradation: Reducing the H2O + CO2 conversion from 56% of a gas flow “parallel” case (Cell P) to 28% in the upstream of the series connected cells (Cell SU) and 39% in the downstream one (Cell SD) reduces the overall cell voltage degradation rate from 372 mV/kh for Cell P to140 mV/kh and 69 mV/kh for Cells SU and SD, respectively. This is tentatively ascribed to the “milder” overall conditions realized in the gas flow series case, where the average as well as maximum polarization (and local current density) is reduced relative to the parallel flow case.

Highlights

The transition from a fossil fuel energy system to one based on renewable energy sources is widely accepted as a need for reducing the global anthropogenic CO2 emission
The results show that a gas-flow series arrangement is advantageous as it leads to reduced cell degradation: Reducing the H2O + CO2 conversion from 56% of a gas flow “parallel” case (Cell P) to 28% in the upstream of the series connected cells (Cell SU) and 39% in the downstream one (Cell SD) reduces the overall cell voltage degradation rate from 372 mV/kh for Cell P to140 mV/kh and 69 mV/kh for Cells SU and SD, respectively
This is tentatively ascribed to the “milder” overall conditions realized in the gas flow series case, where the average as well as maximum polarization is reduced relative to the parallel flow case

Summary

Introduction

The transition from a fossil fuel energy system to one based on renewable energy sources is widely accepted as a need for reducing the global anthropogenic CO2 emission. Solid oxide cells (SOCs) technology has drawn great interest for such applications in recent years, due to their high power to fuel efficiency and excellent reversibility between solid oxide fuel cell (SOFC) operation mode for power generation and solid oxide electrolysis cell (SOEC) mode for fuel production. High performance and durable operation are the keys to bring down the cost of fuel production from SOECs. Better under standing of the degradation mechanism and further optimizing the operation conditions to reduce degradation will help to advance the SOEC technology to the market

Results

Discussion

Conclusion