Abstract
An inversion procedure for determining a repulsive diatomic molecule potential energy curve and a function of the electronic transition moment operator from structured bound-continuum transition intensity data is proposed. The method is based on the first-order perturbation inversion of node positions differences in an experimental spectrum and its zeroth order simulation. This approach is free from the restrictions of the RKR-like procedure of Child, Essen and Le Roy (J. Chem. Phys. 78 (1983) 6732). The method is tested for the 7Li 2 (3 3 Π g ( ν = 17, N = 0)) → a 3 Σ u + and 7Li 2(3 3 Σ g +( ν = 10, N = 10) → a 3 Σ μ +) model bound-free transitions spectra.
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