Abstract
Abstract The purpose of this instrument is to provide a means to measure the rates of exchange, ΔG, ΔS, and ΔH of water and organic solvent adducts on metal chelates. The instrument employs a pulsed ultrasonic technique which perturbs the equilibrium of a metal chelate and then measures the rate at which it returns to equilibrium. This instrument is 10 times more sensitive than a previous instrument and was tested by examining the vanadium(V) benzo-hydroxamic acid chelate in n-butanol.
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