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Abstract
The conformational mobility of organic molecules largely determines their properties. In this work, we used various theoretical and experimental methods to study the behavior of new complexing agents for trivalent f-elements. We presented a new method of conformational analysis and showed its relationship with complexation in solution. As a result, we proposed a new value Solvent-Corrected Preorganisation Energy (SCPE). The proposed value can be used to assess the efficiency of complexation in the target solvent.
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