Abstract

A comprehensive reaction mechanism of Ti3AlC2 MAX-phase formation from its elemental powders while spark plasma sintering has been proposed. Microstructural evaluation revealed that Al-rich TiAl3 intermetallic forms at around 660 °C once Al melts. Gradual transition from TiAl3 to Ti-rich TiAl and Ti3Al intermetallic phases occurs between 700 °C and 1200 °C through formation of layered structure due to diffusion of Al from periphery toward the centre of Ti particles. Formation of TiC and Ti3AlC transient carbide phases were observed to occur through two different reactions beyond 1000 °C. Initially, TiC forms due to interaction of Ti and C, which further reacts with TiAl and Ti and gives rise to Ti3AlC. Later, Ti3AlC also forms due to diffusion of C into Ti3Al above 1200 °C. Above 1300 °C, Ti3AlC phase decomposes into Ti2AlC MAX-phase and TiC in presence of unreacted C. Finally, Ti2AlC and TiC reacts together to from Ti3AlC2 MAX-phase above 1350 °C and completes at 1500 °C.

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