An environmentally benign process for effective recovery and solidification of Cr from stainless-steel slag

Abstract

Stainless-steel slag is a hazardous solid that has caused severe chromium contamination globally. This study proposes an environmentally benign vitrification process for efficient recycling and solidification of Cr from stainless-steel slag using waste copper slag and coal tar residue. The transformation behaviors of heavy metals (Cr, Cu, Pb, Zn) and the Cr toxic leaching mechanism are also determined in this work. The findings indicated that compared with Cu and Fe phases, the Mg(Al,Cr)2O4 and chemically dissolved Cr phases were not easily reduced via coal tar residue, leading to the leaching of highly toxic Cr3+/Cr6+ during the toxicity characteristic leaching procedure (TCLP). Under optimal conditions, 95.56% Cr, 97.71% Fe, and 99.71% Cu could be recovered in the form of high value-added crude stainless-steel, and 99.62% Pb and 99.19% Zn could be enriched in the dust. The furnace slag TCLP result indicated that the leaching concentrations of Cr, Cu, Pb and Zn were 1.82 mg/L, 0.1 mg/L, 0.38 mg/L, and 2.58 mg/L, respectively. More importantly, the concentrations of residual Cr, Cu, Pb and Zn in the furnace slag were only 0.095 wt%, 0.028 wt%, 0.0192 wt%, and 0.011 wt%, respectively. These findings indicate that treated slag can be categorized as general solid waste, minimizing the environmental risks of heavy metals. The results of this study are significant for the sustainable development of the stainless-steel industry and copper metallurgy.