Abstract

Abstract The internal rotation of l,4-dichloro-2-butyne was investigated by the sector-microphotometer method of electron diffraction, examining the region of smaller scattering angles (q\lesssim15) ; photographs taken at a long camera length were analyzed using a criterion that the “background function” should have no sudden fluctuation. Free internal rotation is in good agreement with the observed scattering data, and a high potential barrier is inconsistent.

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