Abstract

In view of current interest in the problem of free or restricted internal rotation in molecules, we may mention briefly some results which indicate free rotation of methyl groups about the Cd—C bond in cadmium dimethyl. We have already described1 measurements on the rotational fine structure of some vibrational bands of zinc dimethyl and mercury dimethyl, which provided strong evidence for such free internal rotation in these molecules. The infrared absorption spectrum of cadmium dimethyl has now been measured with greater resolving power than that previously used by Gutowsky2, particularly in the region of 3 µ.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.