An efficient β-nucleating agent with high lattice matching rate for plate-like crystallization of polypropylene random copolymer.

Abstract

It is challenging to naturally produce large amounts of β-crystals by directly adding a commercial β-nucleating agent (β-NA) into polypropylene random copolymer (PPR) at present. In this work, a novel rare earth β-NA WBN-28 was directly introduced into PPR to prepare β-PPR with high β-crystal conversion. The results of differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD) indicated that it is an efficient β-NA for PPR. The β-conversion rate (β-CR) could surpass 85% when the nucleating agent content was mere 0.05%. With the further increment of nucleating agent, the β-CR increased gradually, which could reach 89.5% and 86.9% respectively calculated by DSC and WAXD when the addition amount was 0.4%. The incredible high β-CR delayed the βα-recrystallization in isothermal crystallization. The fusion peak of α-crystal was unobserved below the isothermal crystallization temperature of 122 °C when the addition amount was more than 0.2%. Furthermore, there was a highly ordered structure in WBN-28 with the periodicity of 12.89 Å, which was approximately twice of the unit cell parameter in the c direction of β-PP, indicating a high lattice matching rate between them. Intuitively observed by polarizing optical microscope (POM), the crystal grains of the blends with β-NA were more refined and finally crystallized in a plate-like shape. The forming process of the plate-like β crystalline regions were proposed by scanning electron microscope (SEM) and POM.