Abstract
In recent years, interest in green solvents, which are environmentally friendly, easy to prepare and biodegradable, and in their applications in chemistry has considerably increased. In the current study, a new and easy deep eutectic solvent-based liquid-phase microextraction method compatible with green chemistry principles was developed for preconcentration of Pb (II) ions. The amount of Pb (II) ions was determined with graphite furnace atomic absorption spectrometry (GFAAS). Various analytical parameters such as deep eutectic solvent (DES) ratio and amount, ligand amount, pH, sample volume were optimized and the effects of potential matrix ions on the method were investigated. The preconcentration factor of the method was found to be 160, while the limit of detection (LOD) and limit of quantification (LOQ) were found to be 0.071µg L-1 and 0.236µg L-1, respectively. The developed procedure was performed to determine Pb (II) ions in lake and river waters, and the accuracy of the procedure was determined with certified reference wastewater (SPS-WW1) analysis.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.