Abstract

The Mediterranean basin is considered a global hot-spot region for climate change and air quality, especially concerning summer-time ozone (O3). Previous investigations indicated that the Mediterranean basin is a preferred region for stratosphere-to-troposphere exchange (STE) and deep stratospheric intrusion (SI) events. The Lagrangian tool STEFLUX, based on a STE climatology that uses the ERA Interim data, was hereby used to diagnose the occurrence of deep SI events in four mountain regions over the Italian peninsula, spanning from the Alpine region to the southern Apennines. By using near-surface O3 and relative humidity (RH) observations at three high-mountain observatories, we investigated the performance of STEFLUX in detecting deep SI events. Both experimental and STEFLUX detections agreed in describing the seasonal cycle of SI occurrence. Moreover, STEFLUX showed skills in detecting “long-lasting” SI events, especially in the Alps and in the northern Apennines. By using STEFLUX, we found positive tendencies in the SI occurrence during 1979–2017. However, in contrast to similar studies carried out in the Alpine region, the negative long-term (1996–2016) trend of O3 in the northern Apennines did not appear to be related to the SI’s variability.

Highlights

  • The Mediterranean basin is considered a global hot-spot region for climate change [1] and air-quality [2]

  • Because a fraction of days was characterized by the lack of simultaneous O3 and relative humidity (RH) measurements at CMP and CUR, we considered a detection algorithm that considers only RH

  • To sites considered in this study, we compared the results of in situ

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Summary

Introduction

The Mediterranean basin is considered a global hot-spot region for climate change [1] and air-quality [2]. Tropospheric ozone (O3 ) is a well-known, short-lived climate forcer and pollutant, which, besides playing a role on regional climate, can have adverse effects on population health and ecosystems [3]. Due to its high oxidizing capacity, it can cause serious health problems, especially respiratory illnesses and cardiovascular diseases, leading to premature death in some cases. It damages vegetation such as forests and agricultural crops and the services they provide, in particular biomass production and carbon sequestration [4].

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