Abstract
We have extended a formalism, developed previously to describe linear systems [H.-C. Chang and W.H. Weinberg, J. Chem. Phys. 66 (1977) 4176; Surface Sci. 65 (1977) 153], to the case of nonlinear reaction models in an analysis of modulated molecular beam mass spectrometry. The formalism is derived explicitly for the case of nonlinear surface reactions, adsorption with a coverage dependent sticking probability, and coupled bulk diffusion and nonlinear reaction. Specific examples illustrating how the formalism may be applied include the catalytic decomposition of formic acid on platinum and the reaction of fluorine with tantalum.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
