Abstract
Piezoelectric sensors convert mechanical stress into electrical charge via the piezoelectric effect, and when fabricated as fibers, they offer flexibility, lightweight properties, and adaptability to complex shapes for self-powered wearable sensors. Polyvinylidene fluoride (PVDF) nanofibers have garnered significant interest due to their potential applications in various fields, including sensors, actuators, and energy-harvesting devices. Achieving optimal piezoelectric properties in PVDF nanofibers requires the careful optimization of polarization. Applying a high electric field to PVDF chains can cause significant mechanical deformation due to electrostriction, leading to crack formation and fragmentation, particularly at the chain ends. Therefore, it is essential to explore methods for polarizing PVDF at the lowest possible voltage to prevent structural damage. In this study, a Design of Experiments (DoE) approach was employed to systematically optimize the polarization parameters using a definitive screening design. The main effects of the input parameters on piezoelectric properties were identified. Heat treatment and the electric field were significant factors affecting the sensor’s sensitivity and β-phase fraction. At the highest temperature of 120 °C and the maximum applied electric field of 3.5 kV/cm, the % β-phase (F(β)) exceeded 95%. However, when reducing the electric field to 1.5 kV/cm and 120 °C, the % F(β) ranged between 87.5% and 90%. The dielectric constant (ɛ′) of polarized PVDF was determined to be 30 at an electric field frequency of 1 Hz, compared to a value of 25 for non-polarized PVDF. The piezoelectric voltage coefficient (g33) for polarized PVDF was measured at 32 mV·m/N at 1 Hz, whereas non-polarized PVDF exhibited a value of 3.4 mV·m/N. The findings indicate that, in addition to a high density of β-phase dipoles, the polarization of these dipoles significantly enhances the sensitivity of the PVDF nanofiber mat.
Published Version
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