Abstract
AbstractFatty acid amides, which contain a saturated or unsaturated alkyl chain derived from a fatty acid, can be divided into three categories. The first is primary monoamides in which R is a fatty alkyl or alkenyl chain of C5C23and R′ = R″ = H. The second is substituted monoamides, including secondary, tertiary, and alkanolamides in which R is a fatty alkyl or alkenyl chain of C5C23; R′ and R″ may be a hydrogen, fatty alkyl, aryl, or alkylene oxide condensation groups with at least one alkyl, aryl, or alkylene oxide group. The third category is bisamides where R groups are fatty alkyl or alkenyl chains. R′ and R″ may be hydrogen, fatty alkyl, aryl, or alkylene oxide condensation groups. Primary and secondary amides show strong hydrogen bonding that account for their high melting points and low solubilities in most solvents. With tertiary amides (disubstituted amides), hydrogen bonding is not possible, as exhibited by their increased solubility and lower melting points. Many fatty acid amides are essentially insoluble in water. Amides have a strong tendency to reduce friction on various surfaces by forming a layer on surfaces. This coating action may be attributed to their hydrophobic character and strong hydrogen bonding. Primary, secondary, and bisamides are widely used as lubricating or slip agents and alkanolamides. Their ethoxylated counterparts are commonly used as surfactants in personal care and detergent applications. Amides in general are stable to elevated processing temperatures, air oxidation, and dilute acids and bases. The dehydration of amides that produces nitriles is of great commercial value. The most widely used synthetic route for primary amides is the reaction of a fatty acid with anhydrous ammonia. Alkanol amides are made from triglycerides or fatty acid methyl esters reacted with monoethanolamine or diethanolamine that then can be ethoxylated with ethylene oxide under basic catalyses. Common products are stearamide, cocamide, ethylene bis(stearamide), cocamide, DEA or MEA, cocamidopropyl dimethyl amine, and cocamide monoethanolamine ethoxylate.
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