Ambient-pressure selective hydrogenation of unsaturated aldehydes and ketones into unsaturated alcohols in the water phase.

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A universal and green catalytic system for the hydrogenation of unsaturated aldehydes and ketones into the corresponding alcohols with the CC bonds retained under atmospheric hydrogen pressure in the water phase was realized by N-functionalized amino ligand-stabilized ruthenium complexes (o-PPh2C6H4NHMe)[(CH2NHR)2]RuCl2 (R = H, Me, Et) and (o-PPh2C6H4NMe2)[(CH2NHEt)2]RuCl2 with wide substrate compatibility and excellent functionality tolerance. The structural synergism between o-PPh2C6H4NHMe and (CH2NHEt)2 achieves the enhanced performance, with a positive correlation with the electron density of the amino ligand.