Abstract
With triallylboron fi-cyc!ocitral gives l-(2,6,6-trimethylcyclohex-l-enyl)but-3-en-l-yl borate, the saponific~t~ion of which yields l-(2,6,6-trimethylcyelohex-l-enyl)but-3-en-l-ol, bp 91-93~ (3 ram), nD 20 1.4950. n-Tributylboron adds to methyl vinyl ketone in the 1,4 position with the formation of oct-2-en-2-yl di-n-butylborinate (V) with bp I00-I03~ (1.5 mm); nD 2~ 1o4300o Found%: C 76.06; H 13.15; B 4.57. CI6H23BOo Calculated%: C 76.13; H 13.18; B 4.36~ The hydrolysis of (V) gives n-hexyl methyl ketone.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
