Abstract
AbstractElectron transfer from an alkali metal to a suitable complexant for the cation can yield crystalline ionic solids that contain the complexed cation and either an alkali metal anion (alkalide) or a trapped electron (electride). The nature and properties of electrides are emphasized in this paper. When the organic complexant contains aromatic groups, the anionic species is an aromatic radical anion. Preliminary work on the addition of alkali metals to LOGEAs (large organic globular electron acceptors) is described and strategies for the synthesis of mixed electride‐anion compounds are considered.
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