Abstract

Two circular Al0.6Ga0.4As p+-i-n+ 2 µm i layer spectroscopic x-ray avalanche photodiodes (one 200 µm diameter and one 400 µm diameter) were made from a structure produced by metalorganic vapour phase epitaxy. The capacitances and currents of the detectors as functions of applied bias were measured, and 55Fe x-ray (Mn Kα = 5.9 keV; Mn Kβ = 6.49 keV) spectra were accumulated at 20 °C (293 K). Improved energy resolutions (measured as the full width at half maximum of the 5.9 keV peak) with increased applied reverse bias were observed with both detectors. In part, the improvement was attributed to avalanche multiplication. Energy resolutions of 630 eV ± 40 eV and 730 eV ± 50 eV were achieved with the 200 µm detector at an applied reverse bias of 38 V and the 400 µm detector at an applied reverse bias of 40 V, respectively. It is the first time Al0.6Ga0.4As has been demonstrated as capable of photon counting x-ray spectrometry. Measurements to determine the average electron-hole pair creation energy in Al0.6Ga0.4As were made; the results suggested a value of 4.97 eV ± 0.12 eV at 25 °C ± 1 °C (298 K ± 1 K). This value was then used to refine the apparent relationship between bandgap energy and electron-hole pair creation energy as defined by the Bertuccio–Maiocchi–Barnett relationship. AlxGa1-xAs x-ray photodiodes of this type are anticipated to be of benefit for future space missions, including those to explore the surfaces of the inner planets (e.g. Mercury and Venus) and the moons of Jupiter and Saturn.

Highlights

  • Two circular Al0.6Ga0.4As p+-i-n+ 2 μm i layer spectroscopic x-ray avalanche photodiodes were made from a structure produced by metalorganic vapour phase epitaxy

  • Measurements to determine the average electron-hole pair creation energy in Al0.6Ga0.4As were made; the results suggested a value of 4.97 eV ± 0.12 eV at 25 ◦C ± 1 ◦C (298 K ± 1 K)

  • Such research has been motivated by the limitations of conventional, relatively narrow bandgap (e.g. Si, e.g. = 1.1 eV [1]) x-ray spectrometers in use today [20, 21], which require cooling and radiation shielding to operate in many environments [22]

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Summary

Introduction

Semiconductor materials with wide bandgaps including SiC [1,2,3], GaAs [4,5,6,7,8], diamond [9, 10], Al0.52In0.48P [11,12,13], In0.5Ga0.5P [14, 15], and AlxGa1-xAs [16,17,18,19] have received extensive study as materials of interest for the manufacture of radiation detectors capable of operating at high (⩾20 ◦C). Even when cooling and radiation shielding are used, the spectral resolution of Si detectors can degrade over time in intense radiation environments, reducing mission lifetime [23]. Wide bandgap materials, such as AlxGa1-xAs, offer an alternative. Since adjusting the Al fraction leads to changes in material and device characteristics (e.g. reducing the Al fraction leads to: a narrower bandgap; an increased linear x-ray absorption coefficient; and a better lattice match with GaAs), it may be beneficial to tailor the Al fraction of AlxGa1-xAs depending on the operating environment. The average electronhole pair creation energy (i.e. the average energy required for the generation of an electron-hole pair at x-ray energies) was experimentally measured for the first time

Detector structure
Measurements of detector capacitance as a function of applied bias
Measurements of detector current as a function of applied bias
Photon counting x-ray spectroscopy
Origin of the secondary peak in the obtained x-ray spectra
Impact ionisation coefficients and multiplication factors
Electron-hole pair creation energy measurements
Findings
Conclusions and further work
Full Text
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