Abstract
We model a macromolecule as an infinitely long Gaussian semi-flexible polymer chain and the conformations of the chain were realized in the nano cube using a cubic lattice. A modified version of the recursion relations is used to calculate the grand canonical partition function of the chain to investigate distinct thermo-dynamical properties of the nano polymer aggregate than corresponding bulk behaviour of the macromolecule. Our analytical estimates on the thermo-dynamical properties of the macromolecule clearly show that the nano aggregate of the polymer chain has interesting and distinct conformational statistics than its corresponding bulk state, and the method described in the present report can be easily extend to investigate the thermodynamics of the self-avoiding polymer chain in the nano dimensions.
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